Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex. Issue 56 (11th June 2020)
- Record Type:
- Journal Article
- Title:
- Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex. Issue 56 (11th June 2020)
- Main Title:
- Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex
- Authors:
- Barnett, Harrison J.
Hill, Anthony F. - Abstract:
- Abstract : Chlorination of the new μ-carbido [Rh2 (μ-C)Cl2 (μ-dppf)2 ] (dppf = 1, 1′-bis(diphenylphosphino)ferrocene) affords the dirhodium(ii ) complex [Rh2 (μ-C)Cl4 (μ-dppf)2 ] the carbido bridge of which can only be adequately described by delocalised bonding. Abstract : The reaction of [Rh2 (μ-C)Cl2 (PPh3 )4 ] with 1, 1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2 (μ-C)Cl2 (μ-dppf)2 ] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii ) carbido complex [Rh2 (μ-C)Cl4 (μ-dppf)2 ].
- Is Part Of:
- Chemical communications. Volume 56:Issue 56(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 56(2020)
- Issue Display:
- Volume 56, Issue 56 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 56
- Issue Sort Value:
- 2020-0056-0056-0000
- Page Start:
- 7738
- Page End:
- 7740
- Publication Date:
- 2020-06-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc02349c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13867.xml