High performance red/deep-red emitting phosphors for white LEDs. (25th March 2020)

• Record Type: Journal Article
• Authors: Rajendran, Marikumar; Vaidyanathan, Sivakumar
• Is Part Of: New journal of chemistry. Volume 44:Number 14(2020)
• Page Start: 5354
• Page End: 5365
• Publication Date: 2020-03-25
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d0nj00086h
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : NaSrGd(MoO4 )3 :Eu 3+ red phosphor exhibits higher quantum efficiency (82%) and the fabricated white LED showed 74% CRI and 6823 K CCT. Abstract : Highly efficient oxide-based red line emitters are still a bottleneck for smart white LEDs. In the present investigation, sequences of narrow band red emitting phosphors were synthesized via the conventional solid-state technique. The X-ray diffraction studies revealed that the as-synthesized phosphors were crystallized in the trigonal phase with the space group I 41 / a (88). Under 395 nm excitation, NaSrGd(MoO4 )3 :Eu 3+ phosphors showed sharp red emission at about 616 nm because of the 5 D0 → 7 F2 transition (ED transition). Moreover, the internal quantum efficiency (IQE) was found to be 82%, and the thermal stability study showed that the NaSrGd0.5 Eu0.5 (MoO4 )3 phosphor retains the emission intensity of about 71.5% of its initial room temperature intensity at 423 K. The red LEDs were designed for the NaSrGd0.5 Eu0.5 (MoO4 )3 red phosphors with the NUV LED chip. White LED was also fabricated by conjugating the blue LED with yellow dye + red phosphor and the LED showed CCT (6823 K), CRI (74%), and CIE (0.306, 0.331). The Sm 3+ and Eu 3+ co-doped deep red phosphor was synthesized and studied in plant growth. The LED emission of Sm 3+ and Eu 3+ co-doped phosphor completely covers the absorption spectrum of Phytochrome Pr. All of these consequences revealed that the as-synthesized phosphor could be an efficient red emitting phosphor for warm white LEDs with application in plant growth research.