Experimental evidence of chalcogen bonding at oxygen. Issue 22 (20th February 2020)

• Record Type: Journal Article
• Authors: Fellowes, Thomas; Harris, Benjamin L.; White, Jonathan M.
• Is Part Of: Chemical communications. Volume 56:Issue 22(2020)
• Page Start: 3313
• Page End: 3316
• Publication Date: 2020-02-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc09896h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An o -nitro-O-aryl oxime was observed to exhibit a short O⋯O contact, which exhibited characteristics consistent with a chalcogen bond. Abstract : An o -nitro-O-aryl oxime was observed to exhibit a short O⋯O contact, which exhibited characteristics consistent with a chalcogen bond. The O–N bond length of the oxime was appreciably longer than the expected value, and NBO calculations indicated the presence of a n(O) → σ(O–N) orbital delocalisation. Topological analysis of the experimental electron density of two analogues shows the presence of a bond path between the two oxygen atoms, with ρ ( r ) and ∇ 2 ρ ( r ) values consistent with an electrostatic interaction. Finally, electrostatic potential calculations indicate the presence of a σ-hole, the "smoking gun" indicating a Ch-bond. These results are unusual as oxygen is not typically considered to be a Ch-bond donor, especially in unactivated systems such as oximes.