Vibrational dynamics in lead halide hybrid perovskites investigated by Raman spectroscopy. Issue 10 (26th February 2020)

• Record Type: Journal Article
• Authors: Ibaceta-Jaña, Josefa; Muydinov, Ruslan; Rosado, Pamela; Mirhosseini, Hossein; Chugh, Manjusha; Nazarenko, Olga; Dirin, Dmitry N.; Heinrich, Dirk; Wagner, Markus R.; Kühne, Thomas D.; Szyszka, Bernd; Kovalenko, Maksym V.; Hoffmann, Axel
• Is Part Of: Physical chemistry chemical physics. Volume 22:Issue 10(2020)
• Page Start: 5604
• Page End: 5614
• Publication Date: 2020-02-26
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c9cp06568g
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The effect of the incorporation of Cs + and Br − in FAPbl3 investigated by Raman spectroscopy. Abstract : Lead halide perovskite semiconductors providing record efficiencies of solar cells have usually mixed compositions doped in A- and X-sites to enhance the phase stability. The cubic form of formamidinium (FA) lead iodide reveals excellent opto-electronic properties but transforms at room temperature (RT) into a hexagonal structure which does not effectively absorb visible light. This metastable form and the mechanism of its stabilization by Cs + and Br − incorporation are poorly characterized and insufficiently understood. We report here the vibrational properties of cubic FAPbI3 investigated by DFT calculations on phonon frequencies and intensities, and micro-Raman spectroscopy. The effects of Cs + and Br − partial substitution are discussed. We support our results with the study of FAPbBr3 which expands the identification of vibrational modes to the previously unpublished low frequency region (<500 cm −1 ). Our results show that the incorporation of Cs + and Br − leads to the coupling of the displacement of the A-site components and weakens the bonds between FA + and the PbX6 octahedra. We suggest that the enhancement of α-FAPbI3 stability can be a product of the release of tensile stresses in the Pb–X bond, which is reflected in a red-shift of the low frequency region of the Raman spectrum (<200 cm −1 ).