A frontier Zn- and N-rich complex grafted onto reduced graphene oxide for the electrocatalysis of dye-sensitized solar cells. Issue 26 (22nd June 2020)

• Record Type: Journal Article
• Authors: Yu, Yuan-Hsiang; Wang, Wun-Shiuan; Hu, Yu-Chung; Lin, Xiao-Yuan; Tsai, Chih-Hung; Shih, Chun-Jyun; Huang, Wei-Chih; Peng, Shie-Ming; Lee, Gene-Hsiang
• Is Part Of: Dalton transactions. Volume 49:Issue 26(2020)
• Page Start: 9035
• Page End: 9047
• Publication Date: 2020-06-22
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d0dt01191f
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A soluble small molecule nitrogen-rich zinc-organic framework for a graphene-based high-efficiency electrocatalytic electrode. Abstract : This paper proposes a novel μ-hydroxo-bridged dinuclear macrocyclic zinc complex, {[Zn(C10 H20 N8 )]2 (OH)}(BF4 )3 . The structure was determined by X-ray crystallography: Monoclinic, C 2/ c, a = 25.4632(6), b = 10.9818(3), c = 15.7522(4) Å, Z = 8, R 1 = 0.0233, w R 2 = 0.0557, based on reflections I > 2 σ ( I ). The complex was successfully reacted with graphene oxide to form a μ-hydroxo-bridged dinuclear macrocyclic Zn complex/reduced graphene oxide composite. To evenly disperse the Zn- and N-rich complex onto the surface of the reduced graphene oxide, and to enhance the electrocatalytic property of the graphene composites, a soluble molecular grafting method was used here. The graphene-based composites were applied as the counter electrodes (CEs) of dye-sensitized solar cells. Current density–voltage measurements revealed that the conversion efficiency of the GO/Zn (1 : 10) sample was 7.78%, which was better than that of Pt CE (7.49%). GO/Zn (1 : 10) CE exhibited the lowest impedance ( R CE = 9.90 Ω), which was better than that of Pt CE ( R CE = 66.1 Ω), showing that GO/Zn CEs can reduce the impedance at the CE/electrolyte interface. The proposed method is simple, and the composite materials can potentially replace conventional Pt, optimizing efficiency and reducing production cost.