A universal strategy to enhance the absolute sensitivity for temperature detection in bright Er3+/Yb3+ doped double perovskite Gd2ZnTiO6 phosphors. (19th February 2020)

• Record Type: Journal Article
• Authors: Wu, Youfusheng; Xu, Shouliang; Xiao, Zhongliang; Lai, Fengqin; Huang, Jianhui; Fu, Junxiang; Ye, Xinyu; You, Weixiong
• Is Part Of: Materials chemistry frontiers. Volume 4:Number 4(2020)
• Page Start: 1182
• Page End: 1191
• Publication Date: 2020-02-19
• Subjects: Materials science -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1039/c9qm00726a
• Languages: English
• ISSNs: 2052-1529

Abstract

Abstract : We report a universal strategy consisting of I 1 / I 2 and I 2 / I 1 parts to enhance the S A for temperature sensing applications. Abstract : The absolute sensitivity as a crucial parameter in temperature detection applications is affected by the fluorescence intensity ratio (FIR) of thermally coupled levels (TCLs), whereas no universal research on the utilization of the FIR effect has been performed to rationally achieve high absolute sensitivity. Herein, a universal strategy on the manipulation of the FIR effect is put forward for the first time. In the Er 3+ -activated Gd2 ZnTiO6 (GZT) system, the maximum absolute sensitivity of 218.8 × 10 −4 K −1 at 313 K is obtained based on this strategy in the 2 H11/2 – 4 S3/2 group, which is enhanced by a factor of 4.6 relative to its original maximum absolute sensitivity. Provably, the maximum absolute sensitivity of 398.7 × 10 −4 K −1 at 313 K in the 2 H11/2 – 4 S3/2 group is gained in the Er 3+ -activated NaYF4 material, which is enhanced by a factor of 12.3. Such high absolute sensitivity is unprecedented in fluoride upconversion (UC) materials. Besides, high sensitivity and excellent UC emissions suggest that the Er 3+ -activated GZT material may be a candidate for temperature detection. This work offers a universal strategy to enhance the absolute sensitivity and maintain the relative sensitivity and opens a new perspective for the development of temperature detection.