Synthesis, electronic structure and physical properties of two new layered compounds, EuFAgSe and EuFAg1−δTe, featuring the active redox pair Eu2+/Ag+. Issue 22 (20th May 2020)

• Record Type: Journal Article
• Authors: Plokhikh, Igor V.; Tsirlin, Alexander A.; Heletta, Lukas; Klenner, Steffen; Charkin, Dmitri O.; Kuznetsov, Alexey N.; Shevelkov, Andrei V.; Pöttgen, Rainer; Pfitzner, Arno
• Is Part Of: Dalton transactions. Volume 49:Issue 22(2020)
• Page Start: 7426
• Page End: 7435
• Publication Date: 2020-05-20
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d0dt01504k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Two layered compounds, EuFAgSe and EuFAg1− δ Te, have been prepared for the first time and their properties have been elucidated. Abstract : Systematic studies of the ZrCuSiAs (also LaOAgS or 1111) structure type resulted in the synthesis of two new fluoride chalcogenides, EuFAgSe and EuFAg1− δ Te, whereas their sulfide analog, EuFAgS, could not be obtained. Both new compounds are tetragonal, P 4/ nmm, with cell parameters a = 4.1542(1) Å, c = 9.2182(1) Å for the selenide and a = 4.3255(1) Å, c = 9.5486(1) Å for the telluride. Rietveld refinement reveals a significant silver deficiency in the telluride ( δ = 0.05), while the selenide is nearly stoichiometric. Both compounds are semiconductors as shown by diffuse reflectance spectroscopy and confirmed by density-functional calculations of the band structure. Magnetism of both compounds is predominantly driven by Eu 2+, as indicated by magnetic susceptibility measurements and corroborated by 151 Eu Mössbauer spectroscopy. EuFAg1− δ Te and EuFAgSe are paramagnetic down to 1.8 K.