Macrocyclization of 3-triflyloxybenzynes with tetrahydrofuran via an anionic thia-Fries rearrangement. Issue 48 (15th May 2020)
- Record Type:
- Journal Article
- Title:
- Macrocyclization of 3-triflyloxybenzynes with tetrahydrofuran via an anionic thia-Fries rearrangement. Issue 48 (15th May 2020)
- Main Title:
- Macrocyclization of 3-triflyloxybenzynes with tetrahydrofuran via an anionic thia-Fries rearrangement
- Authors:
- Cheng, Ruixiang
Xiong, Wenfang
Qi, Chaorong
Wang, Lu
Ren, Yanwei
Jiang, Huanfeng - Abstract:
- Abstract : An uncommon macrocyclization reaction between 3-triflyloxybenzynes and tetrahydrofuran leading to novel 19-membered polyether macrocycles is reported. Abstract : A novel and uncommon macrocyclization reaction between 3-triflyloxybenzynes and tetrahydrofuran has been developed for the first time, providing a direct method for the synthesis of a range of functionalized 19-membered polyether macrocycles in moderate to good yields. The process was proposed to proceed through an anionic thia-Fris rearrangement under transition metal-free conditions, leading to the formation of four new C–O bonds and one new C–S bond in a single step.
- Is Part Of:
- Chemical communications. Volume 56:Issue 48(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 48(2020)
- Issue Display:
- Volume 56, Issue 48 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 48
- Issue Sort Value:
- 2020-0056-0048-0000
- Page Start:
- 6495
- Page End:
- 6498
- Publication Date:
- 2020-05-15
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc00135j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13849.xml