Copper-catalysed Csp3–Csp cross-couplings between cyclobutanone oxime esters and terminal alkynes induced by visible light. Issue 34 (25th March 2020)
- Record Type:
- Journal Article
- Title:
- Copper-catalysed Csp3–Csp cross-couplings between cyclobutanone oxime esters and terminal alkynes induced by visible light. Issue 34 (25th March 2020)
- Main Title:
- Copper-catalysed Csp3–Csp cross-couplings between cyclobutanone oxime esters and terminal alkynes induced by visible light
- Authors:
- Zhao, Binlin
Wu, Yixiao
Yuan, Yu
Shi, Zhuangzhi - Abstract:
- Abstract : A novel transformation for the construction of Csp 3 –Csp bonds was achieved via a photo-induced copper-catalysed C–C bond cleavage. Abstract : A novel transformation for the construction of Csp 3 –Csp bonds was achieved via a photo-induced copper-catalysed C–C bond cleavage. This approach was applied to prepare a series of highly functionalized alkynyl nitriles using readily available cyclobutanones and terminal alkynes. Mechanistic exploration showed that the in situ generated copper acetylide complex is an effective photosensitive catalyst to promote the C–C bond cleavage of cycloketoxime esters through a radical process.
- Is Part Of:
- Chemical communications. Volume 56:Issue 34(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 34(2020)
- Issue Display:
- Volume 56, Issue 34 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 34
- Issue Sort Value:
- 2020-0056-0034-0000
- Page Start:
- 4676
- Page End:
- 4679
- Publication Date:
- 2020-03-25
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc00988a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13847.xml