Constructing multi-cluster copper(i) halides using conformationally flexible ligands. Issue 53 (4th June 2020)

• Record Type: Journal Article
• Authors: Yu, Muxin; Liu, Caiping; Li, Shengchang; Zhao, Yunfang; Lv, Jiangquan; Zhuo, Zhu; Jiang, Feilong; Chen, Lian; Yu, Yunlong; Hong, Maochun
• Is Part Of: Chemical communications. Volume 56:Issue 53(2020)
• Page Start: 7233
• Page End: 7236
• Publication Date: 2020-06-04
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc02472d
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Conformationally flexible ligands were used to trap various Cu(i )-halide clusters in one system to obtain multi-cluster copper(i )-halides with distinctive temperature-dependent luminescence. Abstract : Three unprecedented multi-cluster copper(i ) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(i )-halide clusters in one system, which opens a new way for the construction of multi-Cu(i )-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.