Catalytic sugarcane bagasse transformation into a suitable biocrude for hydrocarbon production in typical refinery processes. Issue 8 (15th June 2020)

• Record Type: Journal Article
• Authors: dos Santos, Débora N.; Pedrosa, Igor V.; Fernandes, Célia R. R.; Lachgar, Abdou; Neli, Marcio; Garrett, Rafael; Lam, Yiu Lau; Pereira, Marcelo M.
• Is Part Of: Sustainable energy & fuels. Volume 4:Issue 8(2020)
• Page Start: 4158
• Page End: 4169
• Publication Date: 2020-06-15
• Subjects: Renewable energy sources -- Periodicals; Fuel cells -- Periodicals; Electric batteries -- Periodicals; Electrochemistry -- Periodicals; 660.297
• DOI: 10.1039/d0se00220h
• Languages: English
• ISSNs: 2398-4902

Abstract

Abstract : A circular economy in a typical refinery. Biomass is converted, under mild conditions into a biocrude with adequate physical–chemical properties to be converted into green hydrocarbons using a typical refinery process. Abstract : The conversion of biomass to green hydrocarbons offers great advantages to shorten our path to sustainability. Unfortunately, none of the existing approaches produces a biocrude that is compatible (in terms of density, viscosity, and reactivity) with current refinery processes. In this work, sugarcane bagasse was converted completely to a biocrude rich in O -isopropylidene acetals by an acetalization process using a continuous flow reactor. Hemicellulose is the first component that transformed into acetals followed by amorphous and crystalline cellulose. Hence, the composition of the biocrude to be collected under specific reaction conditions could be tuned in terms of the type of carbohydrate (pentoses and hexoses) and their derivatives. The process was also applied at a larger scale (20-fold increase) to produce a stable biocrude with density ≈1.2 g cm −3, viscosity of 200 cp (60 °C) and specific heat 1.8 J g °C −1 confirming its properties for conversion in typical refinery processes.