Structural studies of a manganese(iii) complex with spin-crossover and thermochromic properties. Issue 18 (25th April 2020)

• Record Type: Journal Article
• Authors: Villaman, David; McMonagle, Charles J.; Probert, Michael R.; Peña, Octavio; Moreno, Yanko; Fuentealba, Mauricio
• Is Part Of: CrystEngComm. Volume 22:Issue 18(2020)
• Page Start: 3221
• Page End: 3233
• Publication Date: 2020-04-25
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c9ce01962f
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A new Mn III complex exhibits a gradual spin crossover phenomenon with single crystal thermochromism. A comparative structural study was conducted using octahedral deviation parameters. Abstract : Thermochromism and gradual spin crossover (SCO) were observed in the [Mn III (5-MeO-sal-N-1-5-8-12)]Cl complex. The transition temperature ( T 1/2 ) was determined to be 281 K by the drastic changes in the unit cell. This T 1/2 value is the highest observed for this type of system using the 5-MeO-H2 sal-N-(1-5-8-12) ligand. The gradual transition was monitored by single crystal X-ray diffraction at four temperatures (100 K, 290 K, 350 K and 400 K), and the octahedral deviation parameters were obtained to classify the spin state. Moreover, the unit cell parameters were determined at 12 different temperatures from 90 K to 400 K, and significant changes were observed in the unit cell from 250 K to 310 K, corresponding to the low-spin (LS) state to high-spin (HS) state transition or vice versa . Thermochromism in the solid state was observed at cryogenic temperatures, starting at 250 K on a single-crystal sample, representing clear evidence of the electronic transition. This work opens further opportunities to design and synthesize new SCO profiles for Mn III complexes using Schiff base derivatives.