Atomic and electronic structure of solids of Ge2Br2PN, Ge2I2PN, Sn2Cl2PN, Sn2Br2PN and Sn2I2PN inorganic double helices: a first principles study. Issue 25 (14th April 2020)

• Record Type: Journal Article
• Authors: Bijoy, T. K.; Murugan, P.; Kumar, Vijay
• Is Part Of: RSC advances. Volume 10:Issue 25(2020)
• Page Start: 14714
• Page End: 14719
• Publication Date: 2020-04-14
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d0ra02007a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : We report the results of density functional theory calculations on the atomic and electronic structure of solids formed by assembling A2 B2 PN (A = Ge and Sn, B = Cl, Br, and I) inorganic double helices. Abstract : We report the results of density functional theory calculations on the atomic and electronic structure of solids formed by assembling A2 B2 PN (A = Ge and Sn, B = Cl, Br, and I) inorganic double helices. The calculations have been performed using a generalized gradient approximation for the exchange–correlation functional and including van der Waals interactions. Our results show that the double helices crystallize in a monoclinic lattice with van der Waals type weak interactions between the double helices. In all cases except Ge2 Cl2 PN, the solids are stable with a binding energy between the double helices ranging from 0.06 eV per atom to 0.09 eV per atom and inter-double helices separation of more than 3.33 Å. All the solids are semiconducting. Further calculations have been done by using meta-GGA with a modified Becke–Johnson functional to obtain better band gaps, which are found to lie in the range of 0.91 eV to 1.49 eV. In the case of Ge2 Br2 PN the solid is a direct band gap semiconductor although the isolated double helix has an indirect band gap and it is suggested to be interesting for photovoltaic, and other optoelectronic applications. The charge transfer between the atoms has been studied using Bader charge analysis and the DDEC6 method in the CHARGEMOL program, which suggests charge transfer from the outer helix to the inner helix.