Field-induced slow magnetic relaxation in two interpenetrated cobalt(ii) metal–organic framework isomers. Issue 32 (5th August 2020)

• Record Type: Journal Article
• Authors: Wei, Xiao-Qin; Shao, Dong; Xue, Cai-Long; Qu, Xing-Yu; Chai, Jie; Li, Jian-Qing; Du, Yi-En; Chen, Yong-Qiang
• Is Part Of: CrystEngComm. Volume 22:Issue 32(2020)
• Page Start: 5275
• Page End: 5279
• Publication Date: 2020-08-05
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d0ce00979b
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Two interpenetrated cobalt(ii ) metal–organic framework (MOF) isomers were successfully synthesized and magnetically characterized. These compounds are the first example of MOF isomers showing field-induced single-ion magnet behavior. Abstract : Field-induced slow magnetic relaxation was observed in two interpenetrated cobalt(ii ) metal–organic framework (MOF) isomers constructed from a dual-functional ligand 1 H -benzimidazole-5-carboxylic acid, which represent the first example of MOF isomers showing field-induced single-ion magnet behavior.