Highly efficient self-healing materials with excellent shape memory and unprecedented mechanical properties. Issue 32 (29th July 2020)

• Record Type: Journal Article
• Authors: Chen, Chaoxian; Chen, Siwen; Guo, Zhihao; Hu, Wanruo; Chen, Zhangpei; Wang, Jiwei; Hu, Jianshe; Guo, Jing; Yang, Liqun
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 32(2020)
• Page Start: 16203
• Page End: 16211
• Publication Date: 2020-07-29
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0ta04933f
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Novel dual-physical cross-linked elastomers with unprecedented mechanical, highly efficient self-healing, and excellent shape memory properties are designed, which will offer new guild for future body-sensors, stimulating reactive and wound healing. Abstract : Enhancing the mechanical properties and improving the self-healing efficiency are intractable challenges that self-healing materials still need to solve today. In this study, novel dual-physical cross-linked network elastomers with shape memory are designed by introducing dynamic non-covalent bonds via the bulk ring-opening polymerization to improve the mechanical and self-healing properties. The maximum storage modulus and tensile strength of elastomer P4 are 225.82 ± 2.23 MPa and 15.49 ± 0.9 MPa, respectively. Mooney–Rivlin equation calculations indicate that hydrogen bonds and hydrophobic associations play essential roles in reinforcing the mechanical performance and improving the self-healing ability of the elastomers. Meanwhile, elastomer P2 can self-heal after 3 h at room temperature, with a healing efficiency of 95.32%, without requiring any external stimuli. Furthermore, the elastomers present a quick response to body temperature due to the introduction of dynamic non-covalent bonds, resulting in excellent shape memory behavior, and the maximum shape recovery efficiency reaches 72.02 ± 6.94% after 10 s at 37 °C. Further research on the shape recovery time shows that the elastomer can completely recover its original shape after 39.67 ± 1.25 s, indicating a highly efficient shape memory, which offers new directions for future body-sensors, stimuli-responsive materials and wound healing.