Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain. (10th March 2020)

• Record Type: Journal Article
• Authors: Yazaki, Kohei; Takahashi, Masaki; Miyajima, Naoya; Obata, Makoto
• Is Part Of: New journal of chemistry. Volume 44:Number 14(2020)
• Page Start: 5182
• Page End: 5185
• Publication Date: 2020-03-10
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c9nj06394c
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Here we report a new synthetic strategy of a polyMOF consisting of a side chain ligand polymer. The polyMOF was consisting of a crystalline MOF-like structure in the polymer despite its film form. Abstract : The design and synthesis of several types of metal–organic frameworks (MOFs) have been extensively reported in literature. However, the construction of MOFs using a polymer ligand (polyMOF) is still an emerging field of research. This work reports a new molecular synthetic design strategy to produce a polyMOF composed of polymer ligands with a benzenedicarboxylic acid moiety in the side chain. Powder X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy techniques were used to confirm the structures of the resulting polyMOF. Despite the film shape obtained, the resulting Zn-polyMOF showed crystalline structures, per the microscopy images obtained during powder X-ray diffraction.