A germaaluminocene. Issue 11 (21st February 2020)
- Record Type:
- Journal Article
- Title:
- A germaaluminocene. Issue 11 (21st February 2020)
- Main Title:
- A germaaluminocene
- Authors:
- Albers, Lena
Tholen, Patrik
Schmidtmann, Marc
Müller, Thomas - Abstract:
- Abstract : Boron vs. aluminum: the synthesis of a borole complex of Ge(ii ) is reported. Changing just the element from boron to aluminum unexpectedly yields an unprecedented neutral germaaluminocene. Abstract : The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl2 and Cp*AlCl2, yield two structurally different products. In the case of boron a borole complex of germanium(ii ) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.
- Is Part Of:
- Chemical science. Volume 11:Issue 11(2020)
- Journal:
- Chemical science
- Issue:
- Volume 11:Issue 11(2020)
- Issue Display:
- Volume 11, Issue 11 (2020)
- Year:
- 2020
- Volume:
- 11
- Issue:
- 11
- Issue Sort Value:
- 2020-0011-0011-0000
- Page Start:
- 2982
- Page End:
- 2986
- Publication Date:
- 2020-02-21
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0sc00401d ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13954.xml