The improved performance and mechanism of solution-processed blue PhOLEDs based on double electron transport layers. Issue 22 (1st April 2020)

• Record Type: Journal Article
• Authors: Liu, Zijian; Zheng, WeiYe; Wei, Peng; Xu, Zheng; Song, Dandan; Qiao, Bo; Zhao, Suling
• Is Part Of: RSC advances. Volume 10:Issue 22(2020)
• Page Start: 13215
• Page End: 13222
• Publication Date: 2020-04-01
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d0ra00515k
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The performance is improved in solution-processed blue phosphorescent organic light emitting diodes (PhOLEDs) by adopting double electron transport layers (ETL) strategy. Abstract : Performance improved solution-processed blue phosphorescent organic light emitting diodes (PhOLEDs) are demonstrated by adopting a double electron transport layer (ETL) strategy, which consists of TPBi and an additional Alq3 ETL. With the help of Alq3 ETL, the performance of the optimal device with a double ETL is significantly enhanced. The maximum luminance of OLEDs is improved from 6787 cd m −2 to 13 054 cd m −2, and the maximum current efficiency is increased from 3.9 cd A −1 to 11.4 cd A −1 . Furthermore, the difference of carrier injection in the two types of PhOLEDs is explored by using the transient electroluminescence measurement method. The results imply that double ETL can help to balance electron injection and carrier transport, reduce the interface charge accumulation, leading to a high efficiency. The PL decay of the emission layer with different ETL is detected to analyze the effect of the introduced second ETL layer and the interface on the exciton decay of the emission layer. The results show that the introduced interface in devices with a double ETL has an adverse effect on the exciton emission, which contributes to the serious efficiency roll-off of devices with a double ETL.