High-temperature decomposition of Cu2BaSnS4 with Sn loss reveals newly identified compound Cu2Ba3Sn2S8. Issue 22 (28th May 2020)

• Record Type: Journal Article
• Authors: Márquez, José A.; Sun, Jon-Paul; Stange, Helena; Ali, Hasan; Choubrac, Leo; Schäfer, Stefan; Hages, Charles J.; Leifer, Klaus; Unold, Thomas; Mitzi, David B.; Mainz, Roland
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 22(2020)
• Page Start: 11346
• Page End: 11353
• Publication Date: 2020-05-28
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0ta02348e
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : The decomposition mechanism of Cu2 BaSnS4 is studied by in situ diffraction and fluorescence analysis revealing "Sn loss" and Cu2 Ba3 Sn2 S8 at high temperatures. Abstract : The earth-abundant quaternary compound Cu2 BaSnS4 is being currently studied as a candidate for photovoltaics and as a photocathode for water splitting. However, the chemical stability of this phase during synthesis is unclear. The synthesis of other quaternary tin–sulphur-based absorbers ( e.g., Cu2 ZnSnS4 ) involves an annealing step at high temperature under sulphur gas atmosphere, which can lead to decomposition into secondary phases involving Sn loss from the sample. As the presence of secondary phases can be detrimental for device performance, it is crucial to identify secondary phase chemical, structural and optoelectronic properties. Here we used a combination of in situ EDXRD/XRF and TEM to identify a decomposition pathway for Cu2 BaSnS4 . Our study reveals that, while Cu2 BaSnS4 remains stable at high sulphur partial pressure, the material decomposes at high temperatures into Cu4 BaS3 and the hitherto unknown compound Cu2 Ba3 Sn2 S8 if the synthesis is performed under low partial pressure of sulphur. The presence of Cu4 BaS3 in devices could be harmful due to its high conductivity and relatively lower band gap compared to Cu2 BaSnS4 . The analysis of powder diffraction data reveals that the newly identified compound Cu2 Ba3 Sn2 S8 crystallizes in the cubic system (space group I 4̄3 d ) with a lattice parameter of a = 14.53(1) Å. A yellow powder of Cu2 Ba3 Sn2 S8 has been synthesized, exhibiting an absorption onset at 2.19 eV.