Substrate dependent resistive switching in amorphous-HfOx memristors: an experimental and computational investigation. Issue 15 (16th March 2020)

• Record Type: Journal Article
• Authors: Basnet, Pradip; Pahinkar, Darshan G; West, Matthew P.; Perini, Christopher J.; Graham, Samuel; Vogel, Eric M.
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 15(2020)
• Page Start: 5092
• Page End: 5101
• Publication Date: 2020-03-16
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9tc06736a
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Long-range thermal environment makes significant impact on resistive switching in amorphous-HfO x ( x ∼ 1.8) memristors; and the substrate of low thermal conductivity improved both the digital and analog switching performance. Abstract : While two-terminal HfO x ( x < 2) memristor devices have been studied for ion transport and current evolution, there have been limited reports on the effect of the long-range thermal environment on their performance. In this work, amorphous-HfO x based memristor devices on two different substrates, microscopic glass (∼1 mm) and thin SiO2 (280 nm)/Si, with different thermal conductivities in the range from 1.2 to 138 W m −1 K −1 were fabricated. Devices on glass substrates exhibit lower reset voltage, wider memory window and, in turn, a higher performance window. In addition, the devices on glass show better endurance than the devices on the SiO2 /Si substrate. These devices also show non-volatile multi-level resistances at relatively low operating voltages which is critical for neuromorphic computing applications. A multiphysics COMSOL computational model is presented that describes the transport of heat, ions and electrons in these structures. The combined experimental and COMSOL simulation results indicate that the long-range thermal environment can have a significant impact on the operation of HfO x -based memristors and that substrates with low thermal conductivity can enhance switching performance.