Nickel(ii)-methyl complexes adopting unusual seesaw geometries. Issue 57 (5th February 2020)
- Record Type:
- Journal Article
- Title:
- Nickel(ii)-methyl complexes adopting unusual seesaw geometries. Issue 57 (5th February 2020)
- Main Title:
- Nickel(ii)-methyl complexes adopting unusual seesaw geometries
- Authors:
- Hill, Ethan A.
Zhao, Norman
Filatov, Alexander S.
Anderson, John S. - Abstract:
- Abstract : Tris-carbene borate supported nickel methyl complexes adopt unusual seesaw geometries due to competing electronic and chelate effects. Abstract : We report four-coordinate nickel(ii )-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.
- Is Part Of:
- Chemical communications. Volume 56:Issue 57(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 57(2020)
- Issue Display:
- Volume 56, Issue 57 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 57
- Issue Sort Value:
- 2020-0056-0057-0000
- Page Start:
- 7861
- Page End:
- 7864
- Publication Date:
- 2020-02-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc09249h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13890.xml