Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron(v) species. Issue 60 (26th June 2020)

• Record Type: Journal Article
• Authors: Chandra, Bittu; De, Puja; Sen Gupta, Sayam
• Is Part Of: Chemical communications. Volume 56:Issue 60(2020)
• Page Start: 8484
• Page End: 8487
• Publication Date: 2020-06-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc03071f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Iron complex catalyzed selective oxygenation of unactivated C–H bonds for a series of substrates by dioxygen via the autocatalytic formation of oxoiron(v ) species is reported. Abstract : Selective catalytic oxygenation of unactivated C–H bonds for a series of substrates by dioxygen using iron complexes was performed without the use of a co-reductant. Mechanistic studies indicate that the reaction proceeded via the autocatalytic formation of an oxoiron(v ) intermediate, which brings high regioselectivity and stereoretention.