Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation. (5th March 2020)

• Record Type: Journal Article
• Authors: Zhao, Di; Zhuang, Zewen; Cao, Xing; Zhang, Chao; Peng, Qing; Chen, Chen; Li, Yadong
• Is Part Of: Chemical Society reviews. Volume 49:Number 7(2020)
• Page Start: 2215
• Page End: 2264
• Publication Date: 2020-03-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cs00869a
• Languages: English
• ISSNs: 0306-0012

Abstract

Abstract : This review summarized the fabrication routes and characterization methods of atomic site electrocatalysts (ASCs) followed by their applications for water splitting, oxygen reduction and selective oxidation. Abstract : Electrocatalysis plays a central role in clean energy conversion, enabling a number of processes for future sustainable technologies. Atomic site electrocatalysts (ASCs), including single-atomic site catalysts (SASCs) and diatomic site catalysis (DASCs), are being pursued as economical alternatives to noble-metal-based catalysts for these reactions by virtue of their exceptionally high atom utilization efficiencies, well-defined active sites and high selectivities. In this review, we start from a systematic review on the fabrication routes of ASCs followed by an overview of some new and effective characterization methods to precisely probe the atomic structure. Then we give a comprehensive summary on the current advances in some typical clean energy reactions: water splitting, including hydrogen evolution reaction (HER) and oxygen evolution reaction (OER); oxygen reduction reaction (ORR), including selective 4e − – ORR toward H2 O/OH − and 2e − – ORR toward H2 O2 /HO2 − ; selective electrooxidation of formic acid, methanol and ethanol (FAOR, MOR and EOR). At the end of this paper, we present a brief conclusion, and discuss the challenges and opportunities on the further development of more selective, active, stable and less expensive ASCs.