Insertion of Ni(0) and Pd(0) precursors into the Si–Si bond of a disilane with two hypercoordinate silicon atoms. Issue 60 (25th June 2020)

• Record Type: Journal Article
• Authors: Usui, Ryosuke; Sunada, Yusuke
• Is Part Of: Chemical communications. Volume 56:Issue 60(2020)
• Page Start: 8464
• Page End: 8467
• Publication Date: 2020-06-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc03211e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The activation of the silicon–silicon bond in disilane Ph2 Si(μ-Pz Me2 )2 SiPh2 (1 ), which possesses two five-coordinate silicon centers, was achieved by a reaction with Pd(CN t Bu)2 or in situ generated Ni(0)–NHC precursors of modest steric demand. Abstract : The activation of the silicon–silicon bond in disilane Ph2 Si(μ-Pz Me2 )2 SiPh2 (1 ), which possesses two five-coordinate silicon centers, was achieved by a reaction with Pd(0) or Ni(0) precursors of modest steric demand to afford a dinuclear Pd complex (2 ) or two types of mononuclear Ni complexes (3 and 4 ), respectively.