A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior. Issue 20 (29th April 2020)

• Record Type: Journal Article
• Authors: Ruiz, Javier; Sol, Daniel; Mateo, María A.; Vivanco, Marilín; Badía-Laiño, Rosana
• Is Part Of: Dalton transactions. Volume 49:Issue 20(2020)
• Page Start: 6561
• Page End: 6565
• Publication Date: 2020-04-29
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d0dt01246g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Triangular gold(i ) N -arylimidazolate clusters have been prepared by a pNHC metalation protocol and their photoluminescence has been switched on by the addition of Ag + . Abstract : New trinuclear gold(i ) N -arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2 ] + isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag + cation.