Mechanochemically assisted hydrolysis in the ADOR process. Issue 27 (24th June 2020)

• Record Type: Journal Article
• Authors: Rainer, Daniel N.; Rice, Cameron M.; Warrender, Stewart J.; Ashbrook, Sharon E.; Morris, Russell E.
• Is Part Of: Chemical science. Volume 11:Issue 27(2020)
• Page Start: 7060
• Page End: 7069
• Publication Date: 2020-06-24
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d0sc02547j
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : Efficient hydrolysis of zeolites in the ADOR process using mechanochemistry, including economical enrichment with 17 O for solid-state NMR. Abstract : The ADOR (Assembly-Disassembly-Organisation-Reassembly) process for zeolites has been shown to produce a number of previously unknown frameworks inaccessible through conventional synthesis methods. Here, we present successful mechanochemically assisted hydrolysis of germanosilicate zeolite UTL leading to ADOR products under mild conditions, low amounts of solvent and in short reaction times. The expansion of zeolite synthesis into the realm of mechanochemistry opens up feasible pathways regarding the production of these materials, especially for industrial purposes, as well as an exciting application for economical enrichment of materials with the low natural abundance NMR-active isotope of oxygen, 17 O. The results from mechanochemically assisted hydrolysis differ from those seen in the traditional ADOR approach: differences that can be attributed to a change in solvent availability.