ArNMeCH(SiMe3)2: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes. Issue 54 (4th June 2020)

• Record Type: Journal Article
• Authors: Liu, Shunfa; Yang, Yufan; Gao, Lu; Song, Zhenlei
• Is Part Of: Chemical communications. Volume 56:Issue 54(2020)
• Page Start: 7487
• Page End: 7490
• Publication Date: 2020-06-04
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc02277b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : ArNMeCH(SiMe3 )2 has been developed as a useful precursor of a formal α-aminoalkyl diradical in visible-light-mediated homo-diaddition with two identical alkenes in one-pot, or hetero-diaddition with two different alkenes via a sequential operation. Abstract : ArNMeCH(SiMe3 )2 has been developed as a useful precursor of a formal α-aminoalkyl diradical in Ru(bpy)3 Cl2 -catalzyed addition with alkenes under visible-light-mediated photoredox conditions. This approach leads to homo-diaddition with two identical alkenes in one-pot, or hetero-diaddition with two different alkenes via a sequential operation.