Extended conjugated borenium dimers via late stage functionalization of air-stable borepinium ions. Issue 38 (22nd April 2020)
- Record Type:
- Journal Article
- Title:
- Extended conjugated borenium dimers via late stage functionalization of air-stable borepinium ions. Issue 38 (22nd April 2020)
- Main Title:
- Extended conjugated borenium dimers via late stage functionalization of air-stable borepinium ions
- Authors:
- Adachi, Yohei
Arai, Fuka
Jäkle, Frieder - Abstract:
- Abstract : Conjugated dimeric borenium ions exhibit red-shifted absorptions, enhanced emission, and dramatically lower LUMO energies. Abstract : Applications of highly electron-deficient organoborenium ions in conjugated materials remain scarce due to their low stability toward air and moisture. We report here the preparation of benzo[ d ]dithieno[ b, f ]borepinium ions as air-stable π-conjugated heterocycles and their conversion into the first dimeric borenium cations, which exhibit very low lying LUMOs and enhanced fluorescence as a result of extended conjugation.
- Is Part Of:
- Chemical communications. Volume 56:Issue 38(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 38(2020)
- Issue Display:
- Volume 56, Issue 38 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 38
- Issue Sort Value:
- 2020-0056-0038-0000
- Page Start:
- 5119
- Page End:
- 5122
- Publication Date:
- 2020-04-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc02514c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13827.xml