Precise design and synthesis of Pd/InOx@CoOx core–shell nanofibers for the highly efficient catalytic combustion of toluene. Issue 22 (2nd June 2020)

• Record Type: Journal Article
• Authors: Du, Xuebi; Dong, Fang; Tang, Zhicheng; Zhang, Jiyi
• Is Part Of: Nanoscale. Volume 12:Issue 22(2020)
• Page Start: 12133
• Page End: 12145
• Publication Date: 2020-06-02
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/d0nr02334e
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : In this work, Pd/InO x @CoO x core–shell nanofibers, CoO x @Pd/InO x core–shell nanofibers and Pd/InO x /CoO x nanofibers with different morphologies have been successfully synthesized for the catalytic combustion of toluene. Abstract : In this work, Pd/InO x @CoO x core–shell nanofibers, CoO x @Pd/InO x core–shell nanofibers and Pd/InO x /CoO x nanofibers with different morphologies have been successfully synthesized for the catalytic combustion of toluene. Among them, the Pd/InO x @CoO x core–shell sample is novel and composed of Pd/InO x nanotube cores, CoO x nanocubes and CoO x nanoparticle shells derived from ZIF-67. On the contrary, the CoO x @Pd/InO x core–shell catalyst is assembled by CoO x nanocube cores and Pd/InO x nanotube shells. Finally, the Pd/InO x /CoO x nanofibers as references are synthesized by a method similar to the synthesis of the CoO x @Pd/InO x core–shell sample. Interestingly, the Pd/InO x @CoO x core–shell sample displayed the best activity for toluene oxidation with T 90 = 253 °C, good thermal stability and good cyclic stability during three runs. Through some characterizations, it was verified that the Pd/InO x @CoO x core–shell sample exhibited the best performance for toluene oxidation reactions due to a larger specific surface area, higher reducibility, more abundant structural defects and oxygen vacancies, higher proportion of Pd 0 and Co 3+ species and higher lattice oxygen species than others. Simultaneously, the Pd/InO x @CoO x core–shell sample exhibited good thermal stability and cyclic stability, which might be due to the layer of the CoO x shell to protect the stability of the Pd nanoparticle core.