Combinatorial investigation of structural and optical properties of cation-disordered ZnGeN2. Issue 26 (3rd June 2020)

• Record Type: Journal Article
• Authors: Melamed, Celeste L.; Pan, Jie; Mis, Allison; Heinselman, Karen; Schnepf, Rekha R.; Woods-Robinson, Rachel; Cordell, Jacob J.; Lany, Stephan; Toberer, Eric S.; Tamboli, Adele C.
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 26(2020)
• Page Start: 8736
• Page End: 8746
• Publication Date: 2020-06-03
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0tc01675f
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Cation-disordered ZnGeN2 is found to exhibit structural and optical tunability with cation off-stoichiometry. Abstract : Cation-disordered ZnGeN2 shows promise for application as a blue-green emitter in light-emitting devices, but more foundational work is necessary to understand structure–property relationships. In this work, we present a combinatorial exploration of the experimental phase space of wurtzite (cation-disordered) ZnGeN2 using high-throughput co-sputtering. Structure, morphology and optical properties are explored as a function of cation composition and synthesis temperature. ZnGeN2 is found to crystallize in the wurtzite structure ranging from Zn-rich to Ge-rich compositions. X-ray diffraction refinements reveal a continuous shift in cell volume with off-stoichiometry, indicating alloy-like structural behavior. The optical absorption of all films examined is lower in energy than the value predicted for cation-ordered ZnGeN2, suggesting that cation disorder is decreasing the bandgap. Additionally, the absorption threshold shifts continuously to higher energy for Ge-rich samples, consistent with bandgap shifts due to alloy-like structural behavior. Defect formation energy diagrams are calculated to help guide understanding of off-stoichiometry from a defect complex perspective. This work paves the way toward use of ZnGeN2 as a bandgap-tunable optoelectronic semiconductor.