Facile process to utilize carbonaceous waste as a carbon source for the synthesis of low cost electrocatalyst for hydrogen production. (7th September 2020)

• Record Type: Journal Article
• Authors: Mir, Rameez Ahmad; Kaur, Gurbinder; Pandey, O.P.
• Is Part Of: International journal of hydrogen energy. Volume 45:Number 44(2020)
• Page Start: 23908
• Page End: 23919
• Publication Date: 2020-09-07
• Subjects: Molybdenum carbide -- Carbon coating -- Waste carbon -- Hydrogen production -- Efficient electrocatalyst -- Stability; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2019.11.239
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Low cost non-noble metal electrocatalysts are highly desirable for the sustainable production of hydrogen as a renewable energy source. Molybdenum carbide (Mo2 C) has been considered as the promising non-noble metal electrocatalyst for the hydrogen production via hydrogen evolution reaction (HER) through water splitting. The nanostructured nitrogen (N) incorporated carbon (C) coupled with Mo2 C is the potential candidate to boost the HER activity and electrode material for the energy conversion applications. In this work, nitrogen incorporated carbon coated Mo2 C (Mo2 C@C/N) has been synthesized in an eco-friendly way using waste plastic as the carbon source. The pure phase Mo2 C@C/N has been synthesized at 700 and 800 °C for 10 h. The relatively higher temperature synthesized phase shows enhanced HER activity with lower Tafel slope (72.9 mVdec −1 ) and overpotential of 186.6 mV to drive current density of 10 mAcm −2 . It also exhibits stability up to 2000 cyclic voltammetry (CV) cycles and retains the current density with negligible loss for 10 h. The higher temperature synthesized phase exhibits higher electrochemical active surface area (ECSA) and enhanced HER kinetics. Highlights: Synthesis of Mo2C@C/N at 700 and 800 °C. Use of carbonaceous waste for synthesis of energy materials in an eco-friendly way. Higher temperature synthesized phase exhibits lower Tafel slope and high ELDC value.