Structure and vibrational spectra of ReSe2 nanoplates. (28th May 2020)

• Record Type: Journal Article
• Authors: Yukhymchuk, Volodymyr O.; Kulikov, Leonid M.; Valakh, Mykhailo Y.; Litvinchuk, Alexander P.; Skoryk, Mykola A.; Mazur, Nazar V.; Yefanov, Volodymyr S.; Selyshchev, Oleksandr; Dzhagan, Volodymyr M.; Zahn, Dietrich R.T.
• Is Part Of: Journal of Raman spectroscopy. Volume 51:Number 8(2020)
• Page Start: 1305
• Page End: 1314
• Publication Date: 2020-05-28
• Subjects: density functional perturbation theory -- IR -- normal modes -- ReSe2 nanoplates; Raman spectroscopy -- Periodicals; 535.846
• DOI: 10.1002/jrs.5898
• Languages: English
• ISSNs: 0377-0486

Abstract

Abstract: Theoretical and experimental vibrational spectra of ReSe2 nanocrystals, synthesized by self‐limited chemical vapor deposition (CVD), are reported. Scanning electron microscopy reveals that the nanocrystals have the shape of polygon nanoplates (NPs), 20 nm thick and about 100–300 nm wide. X‐ray diffraction studies determined their triclinic structure (space group, P‐1 [no. 2]). The wavenumbers of the Raman‐ and infrared (IR)‐active phonon modes were calculated using the density functional perturbation theory (DFPT), along with the dispersion curves and phonon density of states. The set of theoretical phonon wavenumbers is found to correlate well with the experimental Raman and IR spectra. We established that, unlike ReS2, ReSe2 does not exhibit a "phonon gap." Several "extra" bands in the experimental Raman spectrum of ReSe2 are argued to be defect‐induced contributions of phonons from F and Q critical points of the Brillouin zone. In addition, the effect of Fermi resonance is observed in the Raman spectrum of the ReSe2 NPs, which manifests itself in an increase of the intensity of second‐order bands due to their interaction with first‐order phonons. Abstract : Theoretical and experimental vibrational spectra of ReSe2 nanocrystals, synthesized by self‐limited chemical vapor deposition (CVD) growth, are reported. For ReSe2, unlike ReS2, there is no "phonon gap." The effect of Fermi resonance is observed in the Raman spectrum of the ReSe2 NPs.