CuWO4 decorated by polypyrrole (PPy) protector/sensitizer for novel photocatalytic and stable water splitting for hydrogen generation. (21st August 2020)

• Record Type: Journal Article
• Authors: Dinh, Pham Hai; Pham, Thanh-Dong; Trung, Do Quang; Van Thuan, Doan; Dieu Cam, Nguyen Thi; Hanh, Nguyen Thi; Van Ha, Hoang; Anh Thu, Ngo Hong; Trang, Hoang Thu; Le Minh Tri, Nguyen
• Is Part Of: International journal of hydrogen energy. Volume 45:Number 41(2020)
• Page Start: 21442
• Page End: 21449
• Publication Date: 2020-08-21
• Subjects: CuWO4 -- Water splitting -- PPy -- Sensitizer -- Protector; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.05.229
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Herein, we used polypyrrole (PPy), a conducting polymer, to decorate on CuWO4 to boost its photocatalytic activity. Then, the synthesized PPy decorated on CuWO4 (PPy/CuWO4 ) materials were applied to photocatalytically split water to produce hydrogen. The study investigated that the used PPy effectively served as a spring-board (sensitizer) to improve charge (e − and h + ) separation of the CuWO4 photocatalyst. The used PPy also effectively increased Fermi level of these separated e − of the CuWO4 . Thus, the PPy/CuWO4 generated large available and strong charges, which effectively split water to generate hydrogen. The optimal PPy decorating content for the highest water splitting efficiency is shown to be 4 wt%. Above the optimal decorating content, these excess PPy covered more CuWO4 surface preventing incident irradiation reaching to the material leading to decrease in photocatalytic efficiency. The H2 generation from photocatalytic water splitting by the 4PPy/CuWO4 were 365 (μmol. g −1 cat. h −1 ). It is further observed that the used PPy, which completely covered the CuWO4 particles, effectively assisted charge transfer for their rapid travel to the polymer surface. Thus, the used PPy successfully prevented contact between charges and CuWO4 to protect the material from self-photocorrosion through water splitting process. Graphical abstract: Image 1 Highlights: Successfully decorated PPy on CuWO4 to enhance its photocatalytic performance. PPy effectively served as a sensitizer to improve charge separation of the CuWO4 . PPy also effectively increased Fermi level of these separated e - of the CuWO4 . PPy/CuWO4 exhibited novel photocatalytic water splitting for hydrogen production. Optimal PPy decorating content for the highest water splitting efficiency was 4 wt%.