Highly Elastic Binder for Improved Cyclability of Nickel‐Rich Layered Cathode Materials in Lithium‐Ion Batteries. Issue 29 (22nd June 2020)

• Record Type: Journal Article
• Authors: Chang, Barsa; Kim, Jaemin; Cho, Yunshik; Hwang, Insu; Jung, Min Soo; Char, Kookheon; Lee, Kyu Tae; Kim, Ki Jae; Choi, Jang Wook
• Is Part Of: Advanced energy materials. Volume 10:Issue 29(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-06-22
• Subjects: cation mixing -- hard segments -- micro‐cracks -- soft segments -- transition metal dissolution; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202001069
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Nickel‐rich layered cathode materials are predominantly used for lithium‐ion batteries intended for electric vehicles owing to their high specific capacities and minimal use of high‐cost cobalt. The intrinsic drawbacks of nickel‐rich layered cathode materials with regard to cycle life and safety have largely been addressed by doping and by applying surface coatings. Here, it is reported that a highly elastic binder, namely spandex, can overcome the problems of nickel‐rich layered cathode materials and improve their electrochemical properties drastically. The high elasticity of spandex allows it to uniformly coat LiNi0.8 Co0.1 Mn0.1 O2 particles via shear force during slurry mixing to protect the particles from undesired interfacial reactions during cycling. The uniform coating of spandex, together with its hydrogen bonding interaction with LiNi0.8 Co0.1 Mn0.1 O2, leads to enhanced particle‐to‐particle interaction, which has multiple advantages, such as high loading capability, superior rate and cycling performance, and low binder content. This study highlights the promise of elastic binders to meet the ever‐challenging criteria with respect to nickel‐rich cathode materials in cells targeting electric vehicles. Abstract : A highly elastic binder is reported for nickel‐rich layered cathodes for lithium‐ion batteries. The high elasticity and strong adhesion ability of the binder induce uniform coverage of the active particles, alleviating undesired interfacial reactions and transition metal dissolution. Accordingly, the cyclability and rate capability are drastically improved even under commercial electrode conditions in terms of areal loading and binder content.