A Low‐Temperature Molecular Precursor Approach to Copper‐Based Nano‐Sized Digenite Mineral for Efficient Electrocatalytic Oxygen Evolution Reaction. Issue 6 (20th February 2020)

• Record Type: Journal Article
• Authors: Chakraborty, Biswarup; Kalra, Shweta; Beltrán‐Suito, Rodrigo; Das, Chittaranjan; Hellmann, Tim; Menezes, Prashanth W.; Driess, Matthias
• Is Part Of: Chemistry, an Asian journal. Volume 15:Issue 6(2020)
• Page Start: 852
• Page End: 859
• Publication Date: 2020-02-20
• Subjects: Copper sulfides -- Single-source precursor -- Digenite -- Electrocatalytic OER -- Non-noble metal catalysis; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.202000022
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: In the urge of designing noble metal‐free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 Cu I (PyHS)}2 ](OTf)2 (1 ), and utilized as an anode material in electrocatalytic OER for the first time. A hot injection of 1 yielded a pure phase and highly crystalline Cu9 S5, which was then electrophoretically deposited (EPD) on a highly conducting nickel foam (NF) substrate. When assessed as an electrode for OER, the Cu9 S5 /NF displayed an overpotential of merely 298±3 mV at a current density of 10 mA cm −2 in alkaline media. The overpotential recorded here supersedes the value obtained for the best reported Cu‐based as well as the benchmark precious‐metal‐based RuO2 and IrO2 electrocatalysts. In addition, the choronoamperometric OER indicated the superior stability of Cu9 S5 /NF, rendering its suitability as the sustainable anode material for practical feasibility. The excellent catalytic activity of Cu9 S5 can be attributed to the formation of a crystalline CuO overlayer on the conductive Cu9 S5 that behaves as active species to facilitate OER. This study delivers a distinct molecular precursor approach to produce highly active copper‐based catalysts that could be used as an efficient and durable OER electro(pre)catalysts relying on non‐precious metals. Abstract : Copper as the topper . The Digenite mineral Cu9 S5 phase has been produced from a molecular Cu I 2 S2 precursor complex and applied for efficient electrocatalytic alkaline oxygen evolution reaction, displaying competent catalytic activity and stability.