Formation and oxidation behavior of Ce-modified MoSi2-NbSi2 coating on niobium alloy. (15th August 2020)

• Record Type: Journal Article
• Authors: Xiao, Lairong; Zhou, Xiaojun; Wang, Yifei; Pu, Rong; Zhao, Gang; Shen, Ziqi; Huang, Yali; Liu, Sainan; Cai, Zhenyang; Zhao, Xiaojun
• Is Part Of: Corrosion science. Volume 173(2020)
• Publication Date: 2020-08-15
• Subjects: Silicide coating -- Niobium alloy -- Oxidation -- MoSi2 -- NbSi2 -- Ce; Corrosion and anti-corrosives -- Periodicals; 620.11223
• DOI: 10.1016/j.corsci.2020.108751
• Languages: English
• ISSNs: 0010-938X

Abstract

Graphical abstract: Highlights: MoSi2 -NbSi2 coating and the Ce-modified MoSi2 -NbSi2 coating were prepared on Nb alloy by a new SS-HAPC method. MoSi2 -NbSi2 coating and the Ce-modified MoSi2 -NbSi2 coating can effectively protect Nb alloy for 24.7 h and 28.5 h at 1600 ℃. Ce promotes the thickness of the coating and plays a role in grain refinement without changing the structure the coating. Abstract: MoSi2 -NbSi2 coating and Ce-modified MoSi2 -NbSi2 coating were prepared on Nb-alloy through a new two-step process, including molybdenum slurry spraying and halide-activated pack cementation. The bare alloy was pulverized after oxidation at 1600 °C for 15 min. The both two coated samples have the effective protection for 24.7 h and 28.5 h with the weight gain rate of 3.578 and 2.947 mg 2 cm −4 h −1, respectively. Ce-modified samples show better performance due to Ce has the ability of grain refinement. The reasons for the excellent performance are the good matching between MoSi2 outer layer and NbSi2 inner layer and the continuous SiO2 oxide scale.