Inside Cover: A Sodalite‐Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster (Angew. Chem. Int. Ed. 31/2020). Issue 31 (4th June 2020)

• Record Type: Journal Article
• Authors: Deng, Chenglong; Sun, Cunfa; Wang, Zhi; Tao, Yunwen; Chen, Yilin; Lin, Jinqing; Luo, Genggeng; Lin, Bizhou; Sun, Di; Zheng, Lansun
• Is Part Of: Angewandte Chemie international edition. Volume 59:Issue 31(2020)
• Page Start: 12546
• Page End: 12546
• Publication Date: 2020-06-04
• Subjects: anionic templates -- cluster compounds -- multi-shell structures -- silver nanoclusters -- silver orthophosphate; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202007212
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : A silver orthophosphate cluster (SOC) can be stabilized in the cavity of a giant silver nanocluster. In their Communication on page 12659, G. Luo, D. Sun, and co‐workers present a multi‐shell 102‐silver nanocluster in which a rare rhombicosidodecahedral 60‐silver nanocluster accommodates an unprecedented sodalite‐type SOC {(Ag3 PO4 )8 } concomitantly encapsulating an octahedral Ag6 core. This study is the first presentation of the SOC concept.