A 3-D porous NiII coordination polymer constructed from oxalate and hydrazine linkers. Issue 7 (2nd April 2020)

• Record Type: Journal Article
• Authors: Yao, Peng-Fei; Meng, Jun-Rong; Tang, Jie; Huang, Jun-Bo; Li, Hai-Ye; Liu, Han-Fu; Bian, He-Dong; Huang, Fu-Ping
• Is Part Of: Journal of coordination chemistry. Volume 73:Issue 7(2020)
• Page Start: 1097
• Page End: 1105
• Publication Date: 2020-04-02
• Subjects: Coordination isomers -- simple linkers -- oxalate -- hydrazine; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2020.1764546
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: A Ni II -MOF, {[Ni(C2 O4 )(N2 H4 )]·2H2 O}n (1 ), was constructed by oxalate and hydrazine under hydrothermal conditions at 130 °C. Single-crystal X-ray structural analysis indicates that 1 has a 3-D porous architecture with (10 3 ) topology based on two kinds of 1-D zigzag [Ni(C2 O4 )]n chains with the same structure but different extension directions in the ab plane separated by N2 H4 linker. 1 reveals antiferromagnetic behavior and thermal stability below 283 °C. Graphical Abstract: