Electrochemical investigation of multi-electron reactions in NaVOPO4 cathode for sodium-ion batteries. (10th August 2020)

• Record Type: Journal Article
• Authors: Liang, Ziteng; Liu, Rui; Xiang, Yuxuan; Zhu, Jianping; Liu, Xiangsi; Ortiz, Gregorio F.; Yang, Yong
• Is Part Of: Electrochimica acta. Volume 351(2020)
• Publication Date: 2020-08-10
• Subjects: Na-ion batteries -- NaVOPO4 -- Multi-electron reactions -- Electrochemical mechanism; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2020.136454
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: Realization of multi-electron reactions per transition metal is an effective strategy to increase the energy density of cathode materials, and comprehensively understanding of their underlying mechanism is necessary to further improve the electrochemical performance of the sodium-ion batteries. Here, we investigate and realize multi-electron reactions in NaVOPO4, which could deliver very high specific capacity. In addition, we explore its electrochemical mechanism in great detail by a series of advanced techniques, including XANES, in situ SXRD, 23 Na, 31 P, and 51 V solid state NMR. The results demonstrate that V 3−δ /V 4+ /V 5+ redox couples can be realized in NaVOPO4, and a biphasic transition followed by a monophasic reaction process occurred during discharge process. Finally, the causes of battery failure are analyzed and corresponding strategies to improve electrochemical performance of NaVOPO4 are discussed.