3D network of V2O5 for flexible symmetric supercapacitor. (20th March 2020)

• Record Type: Journal Article
• Authors: Panigrahi, Karamjyoti; Howli, Promita; Chattopadhyay, Kalyan Kumar
• Is Part Of: Electrochimica acta. Volume 337(2020)
• Publication Date: 2020-03-20
• Subjects: V2O5 -- 3D array/network -- Energy density -- Flexible solid-state symmetric supercapacitor -- Cycling stability; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2020.135701
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: The obstacles, faced by flexible lithium-ion batteries (LIB) for its unambiguous synthesis procedure and low power densities for practical applications escalate the position of flexible supercapacitors (SCs) as a new standalone performer in modern energy storage devices. Additionally, some admirable features like supremacy over energy density, cyclic stability and fast response make SCs a vital aspirant among the energy storage devices. Eying on those advantages of SCs, in this work layered oxide V2 O5 3D array has been grown on carbon fabric. The prepared electrode exhibits a specific capacitance of 1098 F/g at a scan rate of 5 mV/s in 0.5 M K2 SO4 electrolyte at three electrode configurations. Further, a flexible solid-state symmetric supercapacitor (SSSc) has been assembled taking LiCl/PVA gel electrolyte. The fabricated SSSc manifests a maximum energy density of 48.32 Wh/kg at a power density of 0.49 kW/kg. Moreover, the device exhibits 92% capacitance retention at a current density of 15 A/g after 10, 000 cyclic performance. Interconnected network morphology with a large number of cavities/pores actually provides swift access of the electrolyte ions which utterly improves the performance of the electrode when it has been used for energy storage purposes. Graphical abstract: V2 O5 3D network embedded Carbon Fabric for solid state flexible symmetric supercapacitor-based applications. Image 1 Highlights: 3D network of V2 O5 is grown on flexible conducting Carbon Fabric (CF). SDS surfactant plays pivotal role for 3D architecture. V2 O5 @CF based solid-state flexible symmetric supercapacitor has been fabricated. Using potential window of 1.6 V maximum energy density 48.32 Wh/kg is obtained. Sharp-edged V2 O5 3D network can greatly maximize the energy storage performance.