New poly(aryl ether ketone)s containing 2, 6-diphenylpyridyl units and diphenylphosphinophenyl pendant groups. (September 2020)

• Record Type: Journal Article
• Authors: Zhang, Zi-Yang; Sheng, Shou-Ri; Zhang, Xiao-Lan; Pan, Yang; Liu, Xiao-Ling
• Is Part Of: High performance polymers. Volume 32:Number 7(2020)
• Page Start: 753
• Page End: 760
• Publication Date: 2020-09
• Subjects: Poly(arylene ether ketone)s -- 2, 6-diphenylpyridyl units -- diphenylphosphinophenyl pendant groups; Polymerization -- Periodicals; Polymers -- Periodicals; 547.7
• DOI: 10.1177/0954008319901148
• Languages: English
• ISSNs: 0954-0083

Abstract

4-(4-Diphenylphosphino)phenyl-2, 6-bis(4-hydroxyphenyl)pyridine, as a new bisphenol monomer, was prepared from 4-(diphenylphosphino)benzaldehyde and 4-hydroxyacetophenone and used in the preparation of several aromatic poly(ether ketone)s (PEKs) containing 2, 6-diphenylpyridyl units and diphenylphosphinophenyl pendant groups via a nucleophilic aromatic substitution polycondensation with difluorinated aromatic ketones. The polycondensation proceeded quantitatively in tetramethylene sulfone in the presence of anhydrous potassium carbonate and afforded the polymers with high molecular weights. The resulting PEKs are amorphous and exhibit high glass transition temperatures of 209–255°C and 5% weight loss temperatures of 536–554°C with char yields of 57–62% at 800°C in nitrogen. Their high char yields and good limited oxygen index values ranging from 39 to 43 indicated these polymers exhibited good thermal stability and flame-retardant property. All new PEKs were soluble in common organic solvents such as N -methyl-2-pyrrolidone, N, N -dimethylacetamide, and chloroform and could form tough, flexible, and strong films with tensile strengths of 74.6–86.8 MPa, tensile moduli of 2.9–3.6 GPa, and elongations at break of 5–9%.