Solar photocatalytic glycerol reforming for hydrogen production over Ternary Cu/THS/graphene photocatalyst: Effect of Cu and graphene loading. (August 2020)

• Record Type: Journal Article
• Authors: Seadira, Tumelo W.P.; Masuku, Cornelius M.; Scurrell, Michael S.
• Is Part Of: Renewable energy. Volume 156(2020)
• Page Start: 84
• Page End: 97
• Publication Date: 2020-08
• Subjects: Glycerol photo-reforming -- Photocatalytic water splitting -- Hydrogen evolution -- Titania hollow spheres -- Graphene sheets facilitated catalysis; Renewable energy sources -- Periodicals; Power resources -- Periodicals; Énergies renouvelables -- Périodiques; Ressources énergétiques -- Périodiques; 333.794
• DOI: 10.1016/j.renene.2020.04.020
• Languages: English
• ISSNs: 0960-1481

Abstract

Abstract: Ternary Cu/TiO2 /rGO photocatalysts with varying Cu and graphene loadings were prepared by a solvothermal method. Pure anatase TiO2 hollow spheres (THS) were prepared with titanium butoxide, ethanol, ammonium sulphate, and urea via a hydrothermal method; Cu nanoparticles were subsequently loaded on the surface of the hollow spheres by wet impregnation. During the solvothermal process, deposition and well dispersion of Cu–TiO 2 hollow spheres composites onto graphene oxide surface, as well as the reduction of graphene oxide to graphene were achieved. The morphological and structural properties of the prepared samples were characterized by Brunauer-Emmett-Tellet (BET), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), UV–vis DRS, and Photoluminescence (PL). The activity of the prepared catalyst was tested for hydrogen production via simultaneous photocatalytic water-splitting and glycerol reforming under natural solar light irradiation. The excellent photocatalytic activity of the ternary Cu/THS/graphene catalyst is attributed to the graphene sheets, which acts as both storage and transferor of electrons generated at the Cu and TiO2 heterojunction, thus increasing the electron-hole pair separation. Graphical abstract: Image 1 Highlights: A highly active ternary Cu/THS/Graphene catalyst was prepared. Hydrogen production from glycerol with solar light was studied. Optimum Cu and graphene loadings were 0.5 wt% and 4 wt%.respectively. Highest activity of the optimized ternary catalyst is 147, 000 μmol.gcat −1 .