Energy efficient hydrogen drying and purification for fuel cell vehicles. (1st April 2020)

• Record Type: Journal Article
• Authors: Ligen, Yorick; Vrubel, Heron; Girault, Hubert
• Is Part Of: International journal of hydrogen energy. Volume 45:Number 18(2020)
• Page Start: 10639
• Page End: 10647
• Publication Date: 2020-04-01
• Subjects: Pressure swing adsorption -- Alkaline electrolysis -- Hydrogen -- Purification -- Hydrogen refuelling station -- Drying; GC Gas Chromatography -- HRS Hydrogen Refuelling Station -- MS Mass Spectrometry -- PEM Proton Exchange Membrane -- PSA Pressure Swing Adsorption -- TSA Temperature Swing Adsorption -- TVSA Temperature & Vacuum assisted Swing Adsorption -- VPSA Vacuum assisted Pressure Swing Adsorption; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.02.035
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: High-purity standards are required for hydrogen used in fuel cell vehicles. The relative abundance of contaminants is highly influenced by the production pathway. Hydrogen obtained from water electrolysis presents three main pollutants: Nitrogen, Oxygen and Water. Herein, the engineering and implementation of removal techniques in a commercial 50 kW alkaline electrolyzer are reported. The full system was characterized with various analytical techniques including gas chromatography and mass spectrometry. A reduction of contaminant levels compatible with ISO 14687:2019 standard was achieved. From cold start, 100 min of operation are required to reach the desired nitrogen levels. Oxygen was removed in one step with a catalytic converter. Drying of hydrogen was achieved by using an innovative vacuum assisted pressure swing adsorption system. Sub-ppm levels of water are obtained with a power consumption of only 0.5 kWh/kg H2 and 98.4% of product recovery. Graphical abstract: Image 1 Highlights: A novel highly efficient vacuum assisted PSA dryer with 98.4% recovery was developed. Post treatments in alkaline electrolysis to reach ISO14687 quality are discussed. Analytical strategies for measurement of nitrogen, oxygen and moisture in hydrogen. Process engineering and validation on a 50 kW alkaline electrolyzer.