Experimental study on the optimisation of azo-dyes removal by photo-electrochemical oxidation with TiO2 nanotubes. (June 2020)

• Record Type: Journal Article
• Authors: Mais, Laura; Vacca, Annalisa; Mascia, Michele; Usai, Elisabetta Maria; Tronci, Stefania; Palmas, Simonetta
• Is Part Of: Chemosphere. Volume 248(2020)
• Publication Date: 2020-06
• Subjects: Advanced oxidation -- Photo-electrochemical degradation -- Azo-dyes -- Design of experiments -- TiO2 nanotubes; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2020.125938
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: An experimental investigation is here presented on the photo-electrochemical removal of Methyl Orange (MO), selected as a model of the organic dyes, contained in wastewaters. The process is carried out in an electrochemical flow reactor, in which titania nanotubular electrode is irradiated with a simulated solar light. Design of Experiments (DOE) technique is used to plan the experimental campaign and investigate on the single and combined effects of applied current, electrolyte flow rate, and initial MO concentration, on the specific reaction rate. The results of the DOE analysis, also combined with the study of the distribution of the intermediate products, confirm a reaction mechanism mediated by OH radicals; high applied current and low reactant concentration resulted as favourable conditions to achieve high specific reaction rate of color removal. Highlights: Photoelectrochemical oxidation of azo dyes has been performed at TiO2 NT electrodes. Design of Experiments is used to organize the experimental campaign. Methyl orange removal is mediated by OH radicals. Aromatic and aliphatic compounds have been detected as reaction intermediates.