Α-Fe2O3/BiFeO3 composites as visible-active photocatalysts and their optical response mechanism. (June 2020)

• Record Type: Journal Article
• Authors: Zhang, Rui; Liu, Saiwei; Kong, Fan; Tong, Junwei; Ruan, Liuxia; Duan, Qingqing; Zhou, Jun; Zhang, Xianmin
• Is Part Of: Journal of physics and chemistry of solids. Volume 141(2020)
• Publication Date: 2020-06
• Subjects: BiFeO3 -- α-Fe2O3 -- Hydrothermal synthesis -- Photocatalytic activity; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2019.109329
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: α-Fe2 O3 /BiFeO3 (BFO) composites have been prepared by loading α-Fe2 O3 onto the surface of BFO via a two-step hydrothermal method. The composites have been systematically investigated by X-ray diffraction (XRD) technique, field emission scanning electron microscopy, energy dispersive spectrometer, UV–vis spectra and X-ray photoemission spectroscopy (XPS). It is observed that all of α-Fe2 O3, BFO and α-Fe2 O3 /BFO composites show a very high purity as detected by XRD. The band gap energies of composites calculated by the UV–visible spectra are smaller than those of both α-Fe2 O3 and BFO, which enhances the visible light absorption capability. The photocatalytic degradation of Rhodamine B under visible light irradiation showed that the efficiency of α-Fe2 O3 /BFO composite could be enhanced than that of both α-Fe2 O3 and BFO. The photocatalytic reaction mechanism of the composites was analyzed based on the position of energy bands as characterized by XPS measurement.