Boron nitride–nanosheet enhanced cellulose nanofiber aerogel with excellent thermal management properties. (1st August 2020)

• Record Type: Journal Article
• Authors: Liu, Ya; Zhang, Yipeng; Liao, Tougen; Gao, Li; Wang, Meng; Xu, Xu; Yang, Xinxin; Liu, He
• Is Part Of: Carbohydrate polymers. Volume 241(2020)
• Publication Date: 2020-08-01
• Subjects: Cellulose nanofibers -- Boron nitride nanosheets -- Thermal conductivity -- Aerogel; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.116425
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: Thermally conductive aerogels are prepared from CNFs and BNNSs. CNFs is used to prepare 3D skeletons and stabilized the dispersion of BNNSs. The 3D structure is beneficial for improving thermal transfer efficiency per unit mass. The aerogels show excellent thermal conductivity and increased mechanical properties. Abstract: Boron nitride nanosheets (BNNSs) are desirable materials for thermal management applications owing to their excellent thermal conductivity. Such property also related to the increased thermal transfer efficiency per unit mass, which can be improved by constructing three-dimensional (3D) structures. Cellulose nanofibers (CNFs) are often used to prepare 3D skeletons and stabilize the dispersion of inorganic fillers. Therefore, CNF/BNNS aerogels were prepared to disperse BNNS in a 3D network. CNF/BNNS aerogel exhibited a thermal conductivity of 0.57 W m −1 K −1, which is an enhancement of 443 % compared to 0.105 W m −1 K −1 of CNF aerogel. The surface temperature changes of the aerogels were confirmed a strong thermal management capacity. The BNNSs also resulted in the compressive strength increased from 0.25 MPa (CNF aerogel) to 0.37 MPa (CNF/BNNS aerogel). This study provides an effective strategy for the preparation of cellulose-based nanocomposite aerogels with excellent thermal management properties and mechanical properties.