A novel process for recovery of aluminum, iron, vanadium, scandium, titanium and silicon from red mud. Issue 2 (April 2020)

• Record Type: Journal Article
• Authors: Zhu, Xiaobo; Niu, Zepeng; Li, Wang; Zhao, Heng; Tang, Qingjie
• Is Part Of: Journal of environmental chemical engineering. Volume 8:Issue 2(2020)
• Publication Date: 2020-04
• Subjects: Aging -- Leaching -- Polymerization reaction -- Red mud -- Solvent extraction; Chemical engineering -- Environmental aspects -- Periodicals; Environmental engineering -- Periodicals; Chemical engineering -- Environmental aspects; Environmental engineering; Periodicals; 660.0286
• DOI: 10.1016/j.jece.2019.103528
• Languages: English
• ISSNs: 2213-2929

Abstract

Highlights: A novel method for recovery of Al, Fe, V, Sc, Ti and Si from red mud was put forward. The parameters of HCl leaching, solvent extraction, polymerization were investigated for extraction of Al, Fe, V, Sc. The parameters of alkali leaching and aging were investigated for rich material of Ti and Si, respectively. Abstract: A novel process for recovery of aluminum, iron, vanadium, scandium, titanium and silicon from red mud was proposed. The parameters of HCl leaching, solvent extraction, polymerization process, alkali leaching with pressure, and aging process were investigated. The results show that more than 96 % of scandium and vanadium could be leached by using HCl with many aluminum, iron and few titanium and silicon from red mud. More than 97 % of vanadium and scandium was extracted by solvent extraction with mono(2-cthylhexyl)2-cthylhexyl phosphonate (P507), but few other elements from the acid leaching solution. The rich vanadium liquid and rich scandium liquid could be obtained by washing the saturated organic phase. More than 97 % of iron and aluminum could be precipitated as the polyaluminum ferric chloride from the raffinate. The rich titanium material of TiO2 with grade of 62 % was obtained by NaOH leaching with pressure from the acid leaching residue. The white carbon black with purity of 99.5 % was obtained by aging with sulfuric acid solution.