A comparative experimental and theoretical investigation on energy storage performance of CoSe2, NiSe2 and MnSe2 nanostructures. (June 2020)

• Record Type: Journal Article
• Authors: Pathak, Mansi; Tamang, Dipti; Kandasamy, Manikandan; Chakraborty, Bramhananda; Rout, Chandra Sekhar
• Is Part Of: Applied materials today. Volume 19(2020)
• Publication Date: 2020-06
• Subjects: Transition metal diselenides -- Energy storage -- Supercapacitors -- Stability -- Density functional theory; Materials science -- Periodicals; Materials -- Research -- Periodicals; 620.1105
• DOI: 10.1016/j.apmt.2020.100568
• Languages: English
• ISSNs: 2352-9407

Abstract

Graphical abstract: The supercapacitor performance of the transition metal selenides is found to be in the order of CoSe2 > NiSe2 > MnSe2 . Theoretically, the highest specific capacitance of CoSe2 which is attributed due to its larger tunnel size in crystal structure, highest surface area, enhanced DOS near Fermi level and highest quantum capacitance, which justifies experimental findings. Highlights: Comparative energy storage performance of transition metal diselenides (CoSe2, NiSe2 and MnSe2 ). Larger tunnel size, highest surface area, enhanced DOS near Fermi level and highest quantum capacitance for CoSe2 . Better energy storage performance of CoSe2 than NiSe2 and MnSe2 with supported experimental and theoretical observations. Abstract: We have investigated a comparative supercapacitor performance of the transition metal (Co, Ni and Mn) diselenides nanostructures assembled in a symmetric electrode configuration. Supercapacitor electrodes based on the transition metal selenides fabricated on Ni-foam which delivered specific capacitance values of 148, 139 and 50 F/g respectively for CoSe2, NiSe2 and MnSe2 which demonstrates the better performance of CoSe2 as compared to NiSe2 and MnSe2 . Moreover, CoSe2 electrode showed good cycling stability with capacitance retention of 98.46% over 3000 cycles, whereas NiSe2 and MnSe2 showed the cycling stability of 59.44% and 86.70% respectively. We have explored the origin of enhanced energy storage performance of CoSe2 both by supported experiments and density functional theory investigation. For theoretical studies, we have computed electronic and structural properties of CoSe2, NiSe2 and MnSe2, using state of art Density Functional Theory (DFT) simulations. Enhanced density of states around fermi level, largest tunnel size, highest surface area per atom and highest quantum capacitance for CoSe2 justifies superior supercapacitance behavior of CoSe2 compared to NiSe2 and MnSe2 as observed in the experiment. Quantum capacitance is highest for CoSe2 and it follows the trend CoSe2 > NiSe2 > MnSe2, similar to the trend for specific capacitance obtained in the experiment. Thus, the present work on comparative investigation on energy storage performance of transition metal diselenides demonstrate that CoSe2 can be further exploited as a potential material for energy storage application.