Co0·5Ni0·5FeCrO4 spinel nanoparticles decorated with UiO-66-based metal-organic frameworks grafted onto GO and O-SWCNT for gas adsorption and water purification. (September 2020)

• Record Type: Journal Article
• Authors: Ashtiani, S.; Khoshnamvand, M.; Shaliutina-Kolešová, A.; Bouša, D.; Sofer, Z.; Friess, K.
• Is Part Of: Chemosphere. Volume 255(2020)
• Publication Date: 2020-09
• Subjects: Magnetic nanoparticles -- Metal-organic framework -- Graphene oxide -- Oxidized single-walled carbon nanotubes -- Water treatment -- Gas sorption; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2020.126966
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: We report on the synthesis of unique nanocomposites based on graphene oxide (GO) and oxidized single-wall carbon nanotubes (O-SWCNTs) combined with UiO-66-NH2 and UiO-66-COOH metal-organic frameworks (MOFs) decorated onto Co0· 5Ni0 ·5 FeCrO4 spinel magnetic nanoparticles (SMNPs). Novel SMNPs of Co0·5 Ni0·5 FeCrO4, synthesized for the first time by the sol-gel method, exhibited exceptional thermal stability up to 985 °C. To modify the physicochemical properties of the SMNPs and MOFs, hydrophilic Zr-based MOFs were directly decorated onto the SMNP (MOF-d-SMNP) which led to improved dispersion properties and enhanced the catalytic activity of the SMNP by providing additional functional groups and active catalytic sites, along with surface area expansion. The synthesis and decoration were achieved by a hydrothermal process forming covalent bonding of MOFs onto the SMNPs, using O-SWCNTs and GO monolayers as platforms. Such an approach proved to be more effective than direct mixing of nanoparticles with the platforms, as it reduced the aggregation of nanoparticles and improved the dispersion forces of the MOF-d-SMNP. The MOF-d-SMNP/GO and MOF-d-SMNP/O-SWCNT nanocomposite properties were characterized by XRD, SEM-EDS, HRTEM, FTIR, TGA, gravimetric gas sorption and BET techniques. Performed experiments revealed exceptional adsorption capacity and catalytic activity (the reduction of the toxic pollutant 4-nitrophenol to 4-aminophenol). We demonstrated that novel nanocomposite materials MOF-d-SMNP/GO and MOF-d-SMNP/O-SWCNT showed potential for water treatment and gas sorption applications. Exhibited properties make these materials promising candidates for use in applications requiring, for example, catalytic activity at elevated temperatures. Graphical abstract: Image 1 Highlights: Synthesis new Co0·5 Ni0·5 FeCrO4 spinel magnetic nanoparticle decorated with UiO-66-based MOFs. Grafting the nanoparticles on single-walled carbon nanotubes and graphene oxide platforms with straightforward approach. Improve thermal stability, surface area and interface interactions of nanoparticles while decreasing the aggregations. Fabricating the nanocomposites with potential for gas separation and water treatments.