Single and binary ion sorption equilibria of monovalent and divalent ions in commercial ion exchange membranes. (15th May 2020) - Chen, G.Q.
Abstract: The co-ion and counter-ion sorption of monovalent (Na +, K +, Cl − and NO3 − ) and divalent ions (Ca 2+ and SO4 2− ) in commercial Neosepta ion exchange membranes were systemically studied in both single and binary salt systems. The new generation of Neosepta cation exchange membrane (CSE) showed a significant difference in water uptake and co-ion sorption compared to the earlier generation (CMX). Use of the Manning model confirmed that there were significant differences between these membranes, with the estimated value of the Manning parameter changing from 1.0 ± 0.1 for CMX to 2.8 ± 0.5 for CSE. There were fewer differences between the two Neosepta anion exchange membranes, AMX and ASE. In single salt solutions, potassium sorbed most strongly into the cation exchange membranes, but in binary salt mixtures, calcium dominated due to Donnan exclusion at low concentrations. While these trends were expected, the sorption behaviour in the anion exchange membranes was more complex. The water uptake of both AMX and ASE was shown to be the greatest in Na2 SO4 solutions. This strong water uptake was reflected in strong sorption of sulphate ions in a single salt solution. Conversely, in a binary salt mixture with NaCl, sulphate sorption fell significantly at higher concentrations. This was possibly caused by ion pairing within the solution, as well as the strongly hydrophobic nature of styrene in the charged polymer. Water uptake was lowest in NaNO3 solutions, even though sorption of the nitrate ion was comparable to that of chloride in these single salt solutions. In the binary mixture, nitrate was absorbed more strongly than chloride. These results could be due to the low surface charge density of this ion allowing it to bond more strongly with the hydrophobic polymeric backbone at the exclusion of water and other ions. Graphical abstract: Image 1 Highlights: Sorption of monovalent and divalent ions in commercial Neosepta membranes studied. The Manning model used to model water uptake and co-ion sorption. Calcium dominated over sodium and potassium counter-ions in binary salt mixtures. Sulphate counter-ion sorption declined significantly with external salt concentration in binary mixtures. Water uptake in nitrate solutions was low, but nitrate counter-ions were absorbed more strongly than chloride.